Forming Ionic Compounds with Ionic Bonds

Are there spare electrons floating around that non-metals can just grab?



B4.30 Fluorine atom trying to grab an electron
As you may have already guessed, there are not spare electrons floating around for non-metal atoms to grab. The electrons that non-metal atoms need to gain come from metal atoms that need to lose electrons to achieve a full valence. There is a transfer of electrons from a metallic atom to a non-metallic atom, thus creating an ion. Next, there will be an electrostatic attraction between cations (+) and anions (–). This attraction is an ionic bond and results in the formation of ionic compounds.



B4.31 Na giving its electron to F



© Wikimedia Commons
B4.32 Transfer of an electron from Na to F


  Watch This

What Are Ionic Bonds @ Youtube FuseSchool – Global Education 


This video illustrates the formation of ionic bonds. There are a few differences to keep in mind.

1. In the modified Bohr diagrams they use, they place the electrons separate in the first energy level.
2. At times, they place two electrons in one orbital.


 


Forming Ionic Compounds with Ionic Bonds Continued


Ionic compounds do not form individual molecules but rather large crystal lattices. These are repeating patterns of positive and negative ions.

The following model uses just the valence electrons to simplify the diagram.

Please note

  • the transfer of electrons
  • the attraction between cations and anions
  • The large number of ions involved to create a crystal lattice

Ionic formulas do not represent the actual number of each element in the large crystal structure, or else the formula for sodium chloride might be Â«math xmlns=¨http://www.w3.org/1998/Math/MathML¨»«msub»«mi»Na«/mi»«mo»§#8734;«/mo»«/msub»«msub»«mi»Cl«/mi»«mo»§#8734;«/mo»«/msub»«/math»! Ionic formulas are always written as the lowest ratio of cations to anions. In this case, it is a 1:1 ratio; so the formula is NaCl.

Crystal lattices can come in a variety of shapes and ratios of cations to anions.
B4.33 the formation of a crystal lattice

calcium flouride
CaF2
sodium chloride
NaCl
lithium nitride
Li3N
B4.35 Crystal lattice of CaF2
B4.36 Crystal lattice of NaCl
B4.36a Crystal lattice of Li3N

  Watch This

Giant Ionic Structures/Lattices @ YouTube FuseSchool – Global Education 


This video illustrates the formation of crystal lattice structures and the properties that result from these structures.