Module 1  

Lesson 1.1  Introducing the Alkanes



Key Concepts


The alkanes are a class of hydrocarbons that contain only single bonds.  Because they contain single bonds only, alkanes are classified as "saturated".  


 A homologous series is a progression of organic compounds that differ only in the number of repeating units.   In the homologous series shown in the animation below, each alkane has one more CH2 group than the preceding alkane. Keep clicking on the arrow to see the various compounds included in this homologous series.


Study the following table displaying the first ten alkanes.

First Ten Alkanes

IUPAC Name
Molecular Formula
methane CH4(g)
ethane C2H6(g)
propane C3H8(g)
butane C4H10(g)
pentane C5H12(l)
hexane C6H14(l)
heptane C7H16(l)
octane C8H18(l)
nonane C9H20(l)
decane C10H22(l)

Learning Tip

The molecular formula shows the number of each type of atom in a compound.

The prefixes indicating one to ten carbon atoms (shown in red) are the same for all hydrocarbons. Commit them to memory!



Did you notice a pattern between the number of carbon atoms and the number of hydrogen atoms?  The general formula for an alkane is CnH2n+2.  Knowing this pattern can help you identify the family to which a hydrocarbon belongs. This is quite handy for large molecules.  For example, is the compound with the molecular formula C17H36 an alkane? The answer is yes!


Note that some alkanes form cyclical structures called cycloalkanes.  In these structures, the carbon chain forms a closed ring.  Study the examples below depicting cyclopentane  and cyclohexane.  Count the carbons and hydrogens in each molecule.  What do you notice about these molecular formulae?  Do they fit the regular pattern for alkanes?




Fig. 2   Examples of  cycloalkanes 


Although these compounds are classified as saturated, they have a different general formula than other alkanes.  Instead of CnH2n+2, they have the general formula CnH2n.  Can you see why the general formula of cycloalkanes shows two less hydrogen per molecule?



 Read pages 366-367 in your textbook.