Module 2

Lesson 1.5 Introducing the Alcohols



Key Concepts


Alcohols are a family of organic compounds containing one or more hydroxyl functional groups (-OH). The general formula for an alcohol is R-OH. R represents a hydrocarbon.


Fig. 1  General formula

 

Alcohols can be produced by chemical synthesis, or, as is the case in ethanol production, by fermentation.

Alcohols can contain one or more hydroxyl groups.

For example, ethanol contains a single hydroxyl group. It is an important organic compound with many industrial/technological applications. For example, ethanol is added to gasoline to increase the fuel's octane number.






 
 
Fig. 2  ethanol
 
 



Alcohols that contain a single hydroxyl functional group can be classified as primary, secondary, or tertiary depending on the position of the hydroxyl group and the bonding of the structure.

  • Primary alcohols - The hydroxyl group is attached to a terminal carbon.
  • Secondary alcohols - The hydroxyl group is attached to a carbon that is bonded to two other carbon atoms.
  • Tertiary alcohols - The hydroxyl group is bonded to a carbon atom that is bonded to three other carbon atoms.


Fig. 3  butan-1-ol (primary alcohol)



Fig. 4  butan-2-ol (secondary alcohol)


Fig. 5  methylpropan-2-ol (tertiary alcohol)

Some alcohols contain more than one -OH group and are referred to as polyalcohols. For example, ethylene glycol (found in antifreeze) is a polyalcohol.





Fig. 6  ethylene glycol
 
 

   Read pages 425 to 430 in the textbook to learn more about alcohols.