3.1 - Enthalpy of Reaction ∆rH
Module 3
Lesson 3.1 Enthalpy of Reaction, ΔrH
Key Concepts
One method of communicating an enthalpy change involves writing the enthalpy of reaction beside the chemical reaction. The enthalpy change of the reaction is symbolized as ΔrH and is expressed in kJ. If the reaction occurs at SATP, the standard state symbol is also included in the enthalpy symbol (ΔrH°). Sometimes, instead of the subscript r, another letter is used to indicate that type of reaction occurring. (Refer to the Learning Tip at the top of page 489 in the textbook.)
It is not necessary to stipulate which substance in the equation is being considered because the enthalpy change (ΔrH) indicated refers to the reaction equation as a whole.
First, consider the process of photosynthesis:
\( \mathrm { 6CO_2(g) + 6H_2O(l) \rightarrow C_6H_{12}O_6(s) + 6O_2(g) } \)
\( \mathrm { \Delta_rH = +2802.5 kJ } \)
This enthalpy value indicates that 2802.5 kJ of energy are absorbed when 6 moles of CO2(g) reacts with 6 moles of H2O(l) to produce 1 mole of C6H12O6(s) and 6 moles of O2(g).
Next, consider the process of cellular respiration:
This enthalpy value indicates that 2802.5 kJ of energy are released when 1 mole of C6H12O6(s) reacts with 6 moles of O2(g) to produce 6 moles of CO2(g) and 6 moles of H2O(l).
Read pages 496 and 497 in the textbook.